Ludwig Boltzmann

Physics Austrian 1844 – 1906 497 quotes

Founder of statistical mechanics and entropy equation

Quotes by Ludwig Boltzmann

The impossibility of an uncompensated decrease of entropy seems to be reduced to an improbability.

On the Relation between the Second Law of Thermodynamics and Probability Theory 1877

Let us consider a gas enclosed in a vessel. The molecules of the gas are in perpetual motion.

Lectures on Gas Theory 1896

The initial state of the universe must have been one of very low entropy.

Implied in work

I think it is fair to say that the kinetic theory of gases is one of the most beautiful and most successful theories of physics.

On the Development of the Methods of Theoretical Physics 1899

The laws of probability applied to a large number of particles lead inexorably to the laws of thermodynamics.

Paraphrase of work

We must not be surprised that in the course of time contradictions arise between theory and experiment; it is the resolution of these contradictions that leads to progress.

On the Development of the Methods of Theoretical Physics 1899

The theory that heat is motion is the key to understanding the second law.

Paraphrase

The practical importance of the second law is greater than that of the first.

The Second Law of Thermodynamics 1886

Mathematics is, in its way, the poetry of logical ideas.

Attributed

The time variation of the distribution function is determined by collisions.

Boltzmann Equation 1872

I am of the opinion, therefore, that the task of theory consists in constructing a picture of the external world that exists purely internally.

On the Development of the Methods of Theoretical Physics 1899

The assumption of atoms is so natural that one can hardly avoid it.

On the Necessity of Atomic Theories 1895

The entropy is a measure of the probability of a state.

On the Relation between the Second Law of Thermodynamics and Probability Theory 1877

The kinetic theory of gases has brought us closer to the ultimate constituents of matter.

Lectures on Gas Theory 1896

One must not confuse what is improbable with what is impossible.

Paraphrase of statistical mechanics

The hypothesis that gases consist of molecules in rapid motion is in agreement with all known phenomena.

Lectures on Gas Theory 1896

The laws of thermodynamics, as empirically determined, express the approximate and probable behavior of systems of a great many particles.

Paraphrase

A theory is the more impressive the greater the simplicity of its premises, the more different kinds of things it relates, and the more extended its area of applicability.

Attributed

The increase of disorder (entropy) is what distinguishes the past from the future.

Implied in work

I feel like a fossil among the living physicists of today.

Letter 1905